FRONTIER MOLECULAR ORBITALS OF COMMON METAL FRAGMENTS OF
ORGANOMETALLICS
This page connects you to the pages with frontier molecular orbitals of typical molecules with metal in a 6 coordination.
To return to the main table of ligands and complexes click here.
| OCTAHEDRAL COMPLEXES AND FRAGMENTS | MOLECULE | GEOMETRY | MOLECULAR ORBITALS | VIBRATIONS | BOND ORDER | |
| ML6 |
Chromium hexacarbonyl | Chromium hexacarbonyl | ||||
| [Manganese hexacarbonyl]+ | [Manganese hexacarbonyl]+ | |||||
|
[Chromium pentacarbonyl)carbyne]- | |||||
|
[Chromium pentacarbonyl)carbyne]+ | |||||
| [TMM]Fe(CO)3 | [TMM]Fe(CO)3 | [TMM]Fe(CO)3 | ||||
| LOSS OF ONE L |
Square Pyramidal Mn(CO)5 | |||||
| LOSS OF TWO L (CIS) | Fe(CO)4 | |||||
| LOSS OF TWO L (Trans) | Square
Planar [PtCl4]2- |
|||||
| LOSS OF THREE L | ML3 Eg. Fe(CO)3 | Fe(CO)3 |