Progress..2012

Module no.

Projected Date

Title of the module

M1

 

Introduction to Organometallic Compounds, History – Importance Projections – 

M2  

 

Metal carbonyl complexes

M2 

 

Metal carbonyls contd.

M 3

 

Basic reaction types – ligand substitution – Dissociation

M4

  

Metal carbenes etc

M4 

 

Substitutes for carbonyl ligand { CS, CSe, CR2, RNC }

M 5 

 

Why phosphines are good ancillary ligands

M 6 

 

Metal alkyl complexes

 M 7

 

Metal hydrides

M 8

 

M.O. theory of Electron precise & Electron deficient systems
3C-2e bond, 3C-4e bond

M 9

 

Insertion reaction – mechanism of CO insertion

M  10

 

Metal alkene complexes - h2 bonding

M 10

  

Alkenes contd.

M11 

 

n dienes and polyenes

M12 

 

Reactivity changes in coordinated ligands–nucleophilic attack on ligands

M13 

 

Metal-allyls - h 3 complexes

M14 

 

Oxidative addition & Reductive elimination Vaskas complex

M15 

 

Cyclopentadienyl - h 5 – sandwich complexes

M16 

 

Metal arene complexes h6 bonding

M17 

 

Piano stool complexes

M18 

 

The isolobal analogy

 M19 

 

Stoichiometric C-C bond forming reactions

M20 

 

Useful catalytic cycles, Hydrogenation reaction, Isomerisation reaction, etc.

M21 

 

Reppe reaction "Ni & Co" catalysed – synthesis of COT, pyridine

M22

 

Asymmetric Induction