WebMO Job Summary

389: C9H9Co, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C9H9Co
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -1730.8692624 Hartree
ZPE 0.143210 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1730.715699 Hartree
Enthalpy -1730.714755 Hartree
Free Energy -1730.762064 Hartree
Cv 41.209 cal/mol-K
Entropy 99.570 cal/mol-K
Dipole Moment 0.3847 Debye
Server localhost (8805)
CPU time 3357.4 sec

Geometry Sequence Energies

Step Energy  
0 -1730.66756611  
1 -1730.75898107  
2 -1730.83406639  
3 -1730.85514675  
4 -1730.86206050  
5 -1730.86393041  
6 -1730.86533042  
7 -1730.86663128  
8 -1730.86730315  
9 -1730.86828783  
10 -1730.86861530  
11 -1730.86892451  
12 -1730.86906405  
13 -1730.86915280  
14 -1730.86922472  
15 -1730.86924960  
16 -1730.86925351  
17 -1730.86925698  
18 -1730.86925837  
19 -1730.86926007  
20 -1730.86926114  
21 -1730.86926167  
22 -1730.86926200  
23 -1730.86926225  
24 -1730.86926240  
25 -1730.86926240  
26 -1730.86926240  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.02615 0.06758508915
b 1.42233 0.04744382195
c 1.17281 0.03912073065

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 13.6708 0.0016
2 A 163.3794 0.2140
3 A 182.5154 4.2514
4 A 192.2609 0.0127
5 A 207.1462 2.3968
6 A 252.9849 3.9149
7 A 337.3548 0.0511
8 A 347.9618 1.7068
9 A 363.2911 6.1226
10 A 466.5682 9.0443
11 A 473.2669 29.0294
12 A 486.6509 3.1178
13 A 515.4064 4.5456
14 A 585.5101 0.5100
15 A 589.6656 0.2342
16 A 664.1332 39.3723
17 A 666.4905 35.1143
18 A 666.7731 24.0471
19 A 680.7277 2.3161
20 A 744.7379 38.1094
21 A 790.0641 0.1194
22 A 798.7912 14.7901
23 A 809.5888 10.5216
24 A 838.8771 67.0625
25 A 846.1270 30.8843
26 A 853.5029 0.1429
27 A 859.7813 21.3168
28 A 863.9973 2.3275
29 A 913.9528 0.3976
30 A 916.7699 4.7638
31 A 1032.2713 7.2340
32 A 1048.9431 9.8679
33 A 1089.9422 0.0237
34 A 1091.0629 0.0261
35 A 1151.3885 2.1968
36 A 1303.3682 0.0005
37 A 1411.5338 0.8201
38 A 1411.7825 0.7421
39 A 1474.1555 4.5767
40 A 1492.6210 1.2688
41 A 1802.5539 94.6915
42 A 1828.8599 73.6026
43 A 3251.4884 0.0387
44 A 3251.9675 0.0466
45 A 3265.9089 5.4066
46 A 3266.6003 5.0563
47 A 3276.9308 1.8074
48 A 3299.0148 6.6625
49 A 3299.3613 0.7810
50 A 3359.2726 1.7707
51 A 3360.7401 0.7823
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IN SO FAR AS QUANTUM MECHANICS IS CORRECT, CHEMICAL QUESTIONS ARE PROBLEMS IN APPLIED MATHEMATICS. -- EYRING, WALTER, & KIMBALL, 1944