WebMO Job Summary

247: C8H8Ni, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N HF/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C8H8Ni
Symmetry C1
Basis 6-31G(d)
RHF Energy -1813.86917295 Hartree
ZPE 0.136398 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1813.724546 Hartree
Enthalpy -1813.723602 Hartree
Free Energy -1813.766748 Hartree
Cv 31.967 cal/mol-K
Entropy 90.808 cal/mol-K
Dipole Moment 0.0010 Debye
Server AGSIPC-DESKTOP.localdomain (283)
CPU time 905 sec

Geometry Sequence Energies

Step Energy  
0 -1813.86534328  
1 -1813.86766501  
2 -1813.86848321  
3 -1813.86884787  
4 -1813.86903125  
5 -1813.86909941  
6 -1813.86913145  
7 -1813.86915632  
8 -1813.86916861  
9 -1813.86916976  
10 -1813.86917295  
11 -1813.86917295  
12 -1813.86917295  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.75079 0.12511288726
b 1.37911 0.04600215793
c 1.37853 0.04598281122

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 18.3076 0.0000(0.0038)
2 A 168.9876 1.6514(0.0001)
3 A 169.3916 1.5357(0.0002)
4 A 249.4043 0.0001(29.9212)
5 A 397.1248 0.5587(37.6102)
6 A 397.2546 0.3352(51.0074)
7 A 399.7814 0.9156(15.0447)
8 A 451.3855 21.1919(0.5316)
9 A 451.5190 21.2447(0.5234)
10 A 559.1363 0.0069(15.5917)
11 A 606.7585 0.2202(0.0003)
12 A 729.1102 0.0001(0.0547)
13 A 730.6725 0.0062(9.5067)
14 A 732.4098 0.0045(9.0767)
15 A 817.0803 1.4730(0.0001)
16 A 818.6670 1.5216(0.0000)
17 A 910.0671 0.0001(26.4748)
18 A 918.2619 0.0002(0.0102)
19 A 919.4502 3.9178(0.0238)
20 A 921.8597 1.2739(0.0588)
21 A 927.3365 169.6116(0.0001)
22 A 1019.3937 0.0001(0.1038)
23 A 1028.1607 0.0428(9.5140)
24 A 1030.5473 0.0271(9.6295)
25 A 1038.3431 40.9793(0.0070)
26 A 1040.7457 41.3121(0.0109)
27 A 1072.6893 0.0002(7.0400)
28 A 1168.2471 0.0000(38.7716)
29 A 1209.6360 0.2939(0.0800)
30 A 1305.7631 0.0000(0.0003)
31 A 1306.7822 0.0000(0.0000)
32 A 1353.5797 75.9078(0.0000)
33 A 1366.0740 0.0000(87.4824)
34 A 1490.4671 0.0015(39.4308)
35 A 1491.6826 0.0599(1.1828)
36 A 1492.9195 0.0111(38.7977)
37 A 1494.4770 0.0162(0.4479)
38 A 3438.3676 0.0000(1.0002)
39 A 3442.0706 0.0001(249.5996)
40 A 3458.0193 0.0096(83.5262)
41 A 3458.2111 0.0579(81.3292)
42 A 3458.4438 1.9209(2.4371)
43 A 3458.6315 1.9374(0.3734)
44 A 3477.1579 0.2892(0.0015)
45 A 3477.3008 0.0000(386.0374)
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Raman Spectrum  
Peak Width (cm-1)

Quote

ALL OUR THINKING ABOUT NATURE MUST NECESSARILY MOVE IN CIRCLES OR SPIRALS; FOR WE CAN ONLY UNDERSTAND NATURE IF WE THINK ABOUT HER, AND WE CAN ONLY THINK BECAUSE OUR BRAIN IS BUILT IN ACCORDANCE WITH NATURE'S LAWS. -- TIMOTHY FERRIS, "GALAXIES"