WebMO Job Summary

222: CP2TiMe_plus_opt, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C11H13Ti(1+)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -1276.21078273 Hartree
ZPE 0.205340 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1275.993651 Hartree
Enthalpy -1275.992707 Hartree
Free Energy -1276.044794 Hartree
Cv 46.327 cal/mol-K
Entropy 109.626 cal/mol-K
Dipole Moment 0.6613 Debye
Server localhost (546)
CPU time 2412.8 sec

Geometry Sequence Energies

Step Energy  
0 -1276.20016751  
1 -1276.20484800  
2 -1276.20632201  
3 -1276.20738682  
4 -1276.20821276  
5 -1276.20881271  
6 -1276.20939161  
7 -1276.20998355  
8 -1276.21035804  
9 -1276.21055796  
10 -1276.21065466  
11 -1276.21067826  
12 -1276.21067581  
13 -1276.21070676  
14 -1276.21060513  
15 -1276.21072784  
16 -1276.21075467  
17 -1276.21077213  
18 -1276.21077990  
19 -1276.21078243  
20 -1276.21078273  
21 -1276.21078273  
22 -1276.21078273  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.52900 0.05100195016
b 0.83300 0.02778588913
c 0.71516 0.02385516983

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 7.9251 0.0000
2 A' 46.2915 0.4619
3 A' 95.5884 7.3174
4 A' 185.4144 0.4125
5 A" 234.8393 2.6853
6 A" 247.3675 0.9829
7 A' 267.8415 4.5472
8 A" 275.3023 0.0350
9 A" 284.4799 0.0146
10 A' 298.0371 21.8993
11 A' 326.5169 4.6744
12 A' 369.9227 4.8397
13 A" 465.0326 10.3273
14 A" 578.2332 1.8387
15 A" 584.4202 0.3644
16 A' 584.6347 1.6813
17 A' 592.5328 0.0568
18 A' 600.3475 1.4056
19 A" 740.7921 7.8094
20 A" 847.5925 14.9003
21 A" 850.4474 9.7668
22 A' 852.4115 5.6497
23 A' 854.7881 1.0212
24 A" 856.3213 119.5045
25 A" 857.5445 27.5541
26 A' 859.8220 11.2227
27 A' 864.0063 3.4123
28 A" 864.8512 28.6199
29 A' 879.9601 8.3811
30 A" 937.4185 0.0004
31 A" 943.8474 0.0121
32 A' 944.7036 0.4623
33 A' 948.4234 1.8671
34 A" 1040.8521 0.3621
35 A' 1043.5345 21.9171
36 A" 1048.1532 0.7836
37 A' 1050.1165 12.6343
38 A" 1090.1419 0.2800
39 A" 1097.1696 0.0107
40 A' 1099.7352 0.0223
41 A' 1102.0568 0.4686
42 A" 1148.8868 3.4937
43 A' 1151.6581 0.1744
44 A' 1221.5398 18.0334
45 A" 1306.1600 0.0002
46 A' 1307.8533 0.0055
47 A" 1395.5667 1.8257
48 A" 1405.9671 0.9137
49 A' 1406.8845 0.9192
50 A" 1409.7698 1.2116
51 A' 1417.0428 1.6077
52 A" 1481.9088 1.0595
53 A' 1482.7783 11.2007
54 A" 1488.8962 0.9226
55 A' 1489.8331 17.4060
56 A' 1500.7820 14.0132
57 A' 2833.8362 19.2157
58 A' 3134.5586 6.9399
59 A" 3193.1792 7.5495
60 A" 3242.6414 0.0586
61 A' 3243.3018 3.6789
62 A" 3253.8281 0.1700
63 A' 3256.1925 0.8382
64 A" 3261.8673 0.8478
65 A' 3262.1804 9.4023
66 A" 3274.7975 0.2178
67 A' 3277.1685 5.7907
68 A" 3279.6436 1.3065
69 A' 3285.7360 1.3605
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NOTHING RESEMBLES A NEW PHENOMENON AS MUCH AS A MISTAKE. -- ENRICO FERMI (?)