FRONTIER MOLECULAR ORBITALS OF COMMON METAL FRAGMENTS OF ORGANOMETALLICS

This page connects you to the pages with frontier molecular orbitals of typical molecules with metal in a 6 coordination.

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OCTAHEDRAL COMPLEXES AND FRAGMENTS MOLECULE GEOMETRY MOLECULAR ORBITALS VIBRATIONS BOND ORDER






ML6
Chromium hexacarbonyl
Chromium hexacarbonyl








[Manganese hexacarbonyl]+
[Manganese hexacarbonyl]+


[Chromium pentacarbonyl)carbyne]-

[Chromium pentacarbonyl)carbyne]-


[Chromium pentacarbonyl)carbyne]+

[Chromium pentacarbonyl)carbyne]+








[TMM]Fe(CO)3
[TMM]Fe(CO)3 [TMM]Fe(CO)3






LOSS OF ONE L
Square Pyramidal Mn(CO)5



LOSS OF TWO  L (CIS) Fe(CO)4



LOSS OF TWO  L (Trans) Square Planar  [PtCl4]2-




LOSS OF THREE L ML3 Eg. Fe(CO)3
Fe(CO)3